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![(-)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I)](https://assets.fishersci.com/TFS-Assets/CCG/Chemical-Structures/chemical-structure-cas-136705-77-6.jpg-650.jpg)
![(-)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I)](https://assets.fishersci.com/TFS-Assets/CCG/logos/Thermo-Scientific-Stacked.jpg-650.jpg)
(-)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 97%, Thermo Scientific™
POA
Chemical Identifiers
| CAS | 136705-77-6 |
|---|---|
| Molecular Formula | C31H48F3O3P2RhS- |
| Molecular Weight (g/mol) | 722.63 |
| MDL Number | MFCD00269860 |
| InChI Key | XGPXBCKGQLCHDW-KYOOHHHUSA-M |
| Synonym | --1,2-bis 2r,5r-2,5-diethylphospholano benzene cyclooctadiene rhodium i trifluoromethanesulfonate, --1,2-bis 2r,5r-2,5-diethylphospholono benzene cycloactadiene rhodium i trifluoromethanesulfonate, 1z,5z-cycloocta-1,5-diene; 2r,5r-1-2-2r,5r-2,5-diethylphospholan-1-yl phenyl-2,5-diethylphospholane; rhodium; trifluoromethanesulfonate |
| PubChem CID | 5702639 |
| IUPAC Name | (1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-diethylphospholan-1-yl]phenyl]-2,5-diethylphospholane;rhodium;trifluoromethanesulfonate |
| SMILES | CCC1CCC(P1C2=CC=CC=C2P3C(CCC3CC)CC)CC.C1CC=CCCC=C1.C(F)(F)(F)S(=O)(=O)[O-].[Rh] |
Description
This Thermo Scientific brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.
Chemical Identifiers
| 136705-77-6 | |
| 722.63 | |
| XGPXBCKGQLCHDW-KYOOHHHUSA-M | |
| 5702639 | |
| CCC1CCC(P1C2=CC=CC=C2P3C(CCC3CC)CC)CC.C1CC=CCCC=C1.C(F)(F)(F)S(=O)(=O)[O-].[Rh] |
| C31H48F3O3P2RhS- | |
| MFCD00269860 | |
| --1,2-bis 2r,5r-2,5-diethylphospholano benzene cyclooctadiene rhodium i trifluoromethanesulfonate, --1,2-bis 2r,5r-2,5-diethylphospholono benzene cycloactadiene rhodium i trifluoromethanesulfonate, 1z,5z-cycloocta-1,5-diene; 2r,5r-1-2-2r,5r-2,5-diethylphospholan-1-yl phenyl-2,5-diethylphospholane; rhodium; trifluoromethanesulfonate | |
| (1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-diethylphospholan-1-yl]phenyl]-2,5-diethylphospholane;rhodium;trifluoromethanesulfonate |
Specifications
| 136705-77-6 | |
| MFCD00269860 | |
| --1,2-bis 2r,5r-2,5-diethylphospholano benzene cyclooctadiene rhodium i trifluoromethanesulfonate, --1,2-bis 2r,5r-2,5-diethylphospholono benzene cycloactadiene rhodium i trifluoromethanesulfonate, 1z,5z-cycloocta-1,5-diene; 2r,5r-1-2-2r,5r-2,5-diethylphospholan-1-yl phenyl-2,5-diethylphospholane; rhodium; trifluoromethanesulfonate | |
| CCC1CCC(P1C2=CC=CC=C2P3C(CCC3CC)CC)CC.C1CC=CCCC=C1.C(F)(F)(F)S(=O)(=O)[O-].[Rh] | |
| 722.63 | |
| 722.62 | |
| [(R,R)Ethyl-DuPhosRh(COD)]CF3SO3 |
| C31H48F3O3P2RhS- | |
| Air Sensitive | |
| XGPXBCKGQLCHDW-KYOOHHHUSA-M | |
| (1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-diethylphospholan-1-yl]phenyl]-2,5-diethylphospholane;rhodium;trifluoromethanesulfonate | |
| 5702639 | |
| 97% |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Warning
RUO – Research Use Only
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