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  8. (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 98%

(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 98%

Product Code. 11386049
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100 mg
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Product Code. Quantity unitSize
11386049 2 g 2g
11309787 100 mg 100mg
11319787 0.5 g 0.5g
11396049 10 g 10g
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Product Code. 11386049

Brand: Thermo Scientific Alfa Aesar 042119.04

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Description

Chiral catalyst ligand | CAS: 99646-28-3 | C48H40P2 | 678.796 g/mol

(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is used as chiral catalyst ligand. (R)-T-BINAP complexes derived from rhodium precursors are used for the asymmetric hydroformylation of vinyl acetate. It is a catalysts used for reductive amination of ketones, Pt dications for cation trapping, Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 99646-28-3
Molecular Formula C48H40P2
Molecular Weight (g/mol) 678.796
MDL Number MFCD00269856
InChI Key IOPQYDKQISFMJI-UHFFFAOYSA-N
Synonym r-tol-binap, s-tol-binap, s---2,2'-bis di-p-tolylphosphino-1,1'-binaphthyl, 2,2'-bis di-p-tolylphosphino-1,1'-binaphthyl, s-t-binap, rac-tol-binap, r-+-2,2'-bis di-p-tolylphosphino-1,1'-binaphthyl, tol-binap, s-2,2'-bis di-p-tolylphosphino-1,1'-binaphthyl, s-p-tol-binap
PubChem CID 4189906
IUPAC Name [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane
SMILES CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C

Specifications

Melting Point 255°C to 257°C
Color White
Quantity 2 g
Solubility Information Insoluble in water.
Optical Rotation +156°C (c=0.5 in Benzene)
Formula Weight 678.79
Percent Purity 98%
Physical Form Powder
Chemical Name or Material (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl

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