missing translation for 'onlineSavingsMsg'
Learn More
  1. Home
  2. Products
  3. Chemicals
  4. Organic compounds
  5. Unclassified Organic Compounds
  6. p-Benzoquinone, 98+%

p-Benzoquinone, 98+%

Product Code. 11468690
Change view
Click to view available options
Quantity:
100 g
250 g
1000 g
5000 g
Unit Size:
1000g
100g
250g
5000g
Product Code. Quantity unitSize
11468690 100 g 100g
11454544 250 g 250g
11444544 1000 g 1000g
11464544 5000 g 5000g
4 options
This item is not returnable. View return policy
Regulatory: This product is an isolated intermediate transported in accordance with Regulation (EC) 1907/2006 (REACH). All customers must complete a declaration before delivery.

Product Code. 11468690

Brand: Thermo Scientific Alfa Aesar A13162.22

Request Bulk or Custom Format

Please to purchase this item. Need a web account? Register with us today!

This item is not returnable. View return policy
Regulatory: This product is an isolated intermediate transported in accordance with Regulation (EC) 1907/2006 (REACH). All customers must complete a declaration before delivery.

Description

CAS: 106-51-4 | C6H4O2 | 108.096 g/mol

p-Benzoquinone is used as a dienophile in Diels-Alder cycloadditions to prepare naphthoquinones and 1,4-phenanthrenediones. It acts as a dehydrogenation reagent and an oxidizer in synthetic organic chemistry. In the Thiele-Winter reaction, it is involved in the preparation of triacetate of hydroxyquinol by reacting with acetic anhydride and sulfuric acid. It is also used in the synthesis of bromadol and to suppress double- bond migration during olefin metathesis reactions. It is used as a precursor to hydroquinone which finds application in photography and as a reducing agent and an antioxidant in rubber production.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
p-Benzoquinone is used as a dienophile in Diels-Alder cycloadditions to prepare naphthoquinones and 1,4-phenanthrenediones. It acts as a dehydrogenation reagent and an oxidizer in synthetic organic chemistry. In the Thiele-Winter reaction, it is involved in the preparation of triacetate of hydroxyquinol by reacting with acetic anhydride and sulfuric acid. It is also used in the synthesis of bromadol and to suppress double- bond migration during olefin metathesis reactions. It is used as a precursor to hydroquinone which finds application in photography and as a reducing agent and an antioxidant in rubber production.

Solubility
Soluble in water, ethanol, ether, methanol, benzene, acetone and ethyl acetate.

Notes
Light sensitive. Store in cool place. Incompatible and reacts violently with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 106-51-4
Molecular Formula C6H4O2
Molecular Weight (g/mol) 108.096
MDL Number MFCD00001591
InChI Key AZQWKYJCGOJGHM-UHFFFAOYSA-N
Synonym p-benzoquinone, benzoquinone, quinone, 1,4-benzoquinone, p-quinone, chinone, 2,5-cyclohexadiene-1,4-dione, cyclohexadienedione, para-quinone, 1,4-benzoquine
PubChem CID 4650
ChEBI CHEBI:16509
IUPAC Name cyclohexa-2,5-diene-1,4-dione
SMILES C1=CC(=O)C=CC1=O

Specifications

Melting Point 112°C to 115°C
Density 1.318
Boiling Point ∼180°C (sublimation)
Flash Point 77°C (171°F)
Assay Percent Range ≥98%
Odor Pungent
Quantity 100 g
UN Number UN2587
Beilstein 773967
Sensitivity Light sensitive
Merck Index 14,8074
Solubility Information Soluble in water,ethanol,ether,methanol,benzene,acetone and ethyl acetate.
Formula Weight 108.1
Percent Purity ≥98%
Chemical Name or Material p-Benzoquinone
Show More Show Less

Safety and Handling

compliance-icons compliance-icons
Product Identifier
  • p-Benzoquinone
 Signal Word
  • Danger
 Hazard Category
  • Acute toxicity Category 3
  • ACUTE AQUATIC Acute 1
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H301-Toxic if swallowed.
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H331-Toxic if inhaled.
  • H335-May cause respiratory irritation.
  • H400-Very toxic to aquatic life.
 Precautionary Statement
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P273-Avoid release to the environment.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Supplemental information
  • MIXTURE LIST-Contains : Quinone
SDS

RUO – Research Use Only

Product Title
Select an issue

By clicking Submit, you acknowledge that you may be contacted by Fisher Scientific in regards to the feedback you have provided in this form. We will not share your information for any other purposes. All contact information provided shall also be maintained in accordance with our Privacy Policy.