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  6. Dicarbonyl(2,4-pentanedionato)rhodium(I), 97%

Dicarbonyl(2,4-pentanedionato)rhodium(I), 97%

Product Code. 11480221
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Quantity:
250 mg
1 g
5 g
Unit Size:
1g
250mg
5g
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Product Code. 11480221

Brand: Thermo Scientific Alfa Aesar 039295.MD

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Description

CAS: 14874-82-9 | C7H7O4Rh | 258.03 g/mol

(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 14874-82-9
Molecular Formula C7H7O4Rh
Molecular Weight (g/mol) 258.03
MDL Number MFCD00009884
InChI Key BZCAWKOPWNIDOC-FGSKAQBVSA-M
Synonym (Acetylacetonato)dicarbonylrhodium(I), Acetylacetonatorhodium(I) dicarbonyl
IUPAC Name λ¹-rhodium(1+) bis(methanidylidyneoxidanium) (2Z)-4-oxopent-2-en-2-olate
SMILES [Rh+].[C-]#[O+].[C-]#[O+].C\C([O-])=C\C(C)=O

Specifications

Melting Point 144°C to 147° (sublimation)
Color Green
Assay Percent Range 99%
Odor Odorless
Quantity 250 mg
Solubility Information Soluble in acetone
Formula Weight 258.04
Physical Form Crystalline
Chemical Name or Material Dicarbonyl(2, 4-pentanedionato)rhodium(I)

Safety and Handling

compliance-icons compliance-icons
Product Identifier
  • Dicarbonyl(2,4-pentanedionato)rhodium(I)
 Signal Word
  • Danger
 Hazard Category
  • Acute toxicity Category 3
  • LONG-TERM AQUATIC HAZARD Chronic 3
  • Serious eye damage/eye irritation Category 2
  • Flammable solid Category 2
  • Skin sensitiser Category 1
 Hazard Statement
  • H228-Flammable solid.
  • H301-Toxic if swallowed.
  • H317-May cause an allergic skin reaction.
  • H319-Causes serious eye irritation.
  • H412-Harmful to aquatic life with long lasting effects.
  • EUH044-Risk of explosion if heated under confinement.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P333+P313-If skin irritation or rash occurs: Get medical advice/attention.
  • P337+P313-If eye irritation persists: Get medical advice/attention.
 Supplemental information
  • MIXTURE LIST-Contains : Dicarbonyl(2,4-pentanedionato)rhodium(I)
SDS

RUO – Research Use Only

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