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  6. Di-tert-butylchlorophosphine, 96%, Thermo Scientific Chemicals

Di-tert-butylchlorophosphine, 96%, Thermo Scientific Chemicals

Catalog Number 11325349
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Quantity:
1 g
5 g
25 g
This item is not returnable. View return policy
13716-10-4
C8H18ClP
180.656
MFCD00008815
MCRSZLVSRGTMIH-UHFFFAOYSA-N
di-tert-butylchlorophosphine, di-tert-butylchlorophosphane, di-t-butylchlorophosphine, phosphinous chloride, bis 1,1-dimethylethyl, chlorodi-tert-butylphosphine, phosphinous chloride, di-tert-butyl, di-tert-butyl chloro phosphane, di-tert-butylphosphinous chloride, clptbu2, pubchem6477
139566
ditert-butyl(chloro)phosphane
CC(C)(C)P(C(C)(C)C)Cl
This item is not returnable. View return policy
13716-10-4
C8H18ClP
180.656
MFCD00008815
MCRSZLVSRGTMIH-UHFFFAOYSA-N
di-tert-butylchlorophosphine, di-tert-butylchlorophosphane, di-t-butylchlorophosphine, phosphinous chloride, bis 1,1-dimethylethyl, chlorodi-tert-butylphosphine, phosphinous chloride, di-tert-butyl, di-tert-butyl chloro phosphane, di-tert-butylphosphinous chloride, clptbu2, pubchem6477
139566
ditert-butyl(chloro)phosphane
CC(C)(C)P(C(C)(C)C)Cl

Description

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Miscible with terahydrofuran.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.
TRUSTED_SUSTAINABILITY
Density 0.951
Boiling Point 47°C to 49°C (3 mmHg)
Flash Point 62°C (144°F)
Odor Acrid
Linear Formula [(CH3)3C]2PCl
Refractive Index 1.484
Quantity 5 g
UN Number UN3265
Sensitivity Air and moisture sensitive
Solubility Information Miscible with terahydrofuran.
Formula Weight 180.66
Percent Purity 96%
Chemical Name or Material Di-tert-butylchlorophosphine
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