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  7. 3-Bromo-1-trimethylsilyl-1-propyne, 98%

3-Bromo-1-trimethylsilyl-1-propyne, 98%

Product Code. 15440278
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25 g
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Product Code. Quantity unitSize
15440278 25 g 25g
15430278 5 g 5g
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Product Code. 15440278

Brand: Thermo Scientific Alfa Aesar H53451.14

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Description

CAS: 38002-45-8 | C6H11BrSi | 191.143 g/mol

3-Bromo-1-trimethylsilyl-1-propyne is used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It acts as a propargylating agent and used for the alkylation of dianion of beta-keto esters at gamma-carbon. It plays an important role in the synthesis of allenic alcohols and terminal conjugated enynes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3-Bromo-1-trimethylsilyl-1-propyne is used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It acts as a propargylating agent and used for the alkylation of dianion of beta-keto esters at gamma-carbon. It plays an important role in the synthesis of allenic alcohols and terminal conjugated enynes.

Solubility
Immiscible with water.

Notes
Store in cool place. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 38002-45-8
Molecular Formula C6H11BrSi
Molecular Weight (g/mol) 191.143
MDL Number MFCD00134460
InChI Key GAPRPFRDVCCCHR-UHFFFAOYSA-N
Synonym 3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r
PubChem CID 642589
IUPAC Name 3-bromoprop-1-ynyl(trimethyl)silane
SMILES C[Si](C)(C)C#CCBr

Specifications

Boiling Point 44°C to 45°C (2mmHg)
Quantity 25 g
Linear Formula BrCH2C≡CSi(CH3)3
Beilstein 2037650
Flash Point 63°C (145°F)
Solubility Information Immiscible with water.
Formula Weight 191.14
Percent Purity 98%
Refractive Index 1.483
Density 1.17
Chemical Name or Material 3-Bromo-1-trimethylsilyl-1-propyne
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