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1,3-Bis(diphenylphosphino)propane, 97%, Thermo Scientific Chemicals

Catalog Number p-7020841
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Quantity:
5 g
25 g
100 g
This item is not returnable. View return policy
6737-42-4
C27H26P2
412.45
MFCD00003050
LVEYOSJUKRVCCF-UHFFFAOYSA-N
1,3-bis diphenylphosphino propane, dppp, trimethylenebis diphenylphosphine, phosphine, 1,3-propanediylbis diphenyl, 3-diphenylphosphanyl propyl diphenylphosphane, 3-diphenylphosphanylpropyl diphenyl phosphane, 1,3-bis diphenyphosphino propane, 1,3-bis diphenylphosphino propane dppp, bis 1,3-diphenylphosphino propane, 1,3-bis-diphenylphosphino propane
81219
3-diphenylphosphanylpropyl(diphenyl)phosphane
C(CP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1
This item is not returnable. View return policy
6737-42-4
C27H26P2
412.45
MFCD00003050
LVEYOSJUKRVCCF-UHFFFAOYSA-N
1,3-bis diphenylphosphino propane, dppp, trimethylenebis diphenylphosphine, phosphine, 1,3-propanediylbis diphenyl, 3-diphenylphosphanyl propyl diphenylphosphane, 3-diphenylphosphanylpropyl diphenyl phosphane, 1,3-bis diphenyphosphino propane, 1,3-bis diphenylphosphino propane dppp, bis 1,3-diphenylphosphino propane, 1,3-bis-diphenylphosphino propane
81219
3-diphenylphosphanylpropyl(diphenyl)phosphane
C(CP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

Solubility
Insoluble in water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY
Melting Point 58°C to 63°C
Linear Formula (C6H5)2P(CH2)3P(C6H5)2
Quantity 5 g
Beilstein 2821785
Sensitivity Air Sensitive
Solubility Information Insoluble in water.
Formula Weight 412.46
Percent Purity 97%
Chemical Name or Material 1,3-Bis(diphenylphosphino)propane

RUO – Research Use Only

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